Effect of ZnCdTe-Alloyed Nanocrystals on Polymer–Fullerene Bulk Heterojunction Solar Cells

Improvement of light harvesting by inserting an optical spacer (ZnO) in polymer bulk heterojunction solar cells: A theoretical and experimental study

By introducing a thin ZnO layer as an optical spacer, we have demonstrated that inserting this layer between an active layer and a reflective electrode results in a re-distribution of the optical electric field inside bulk heterojunction solar cells. A theoretical analysis by optical modeling showed that the thin ZnO layer could shift the position of the maximum of the electric field into the a...

Studies of Charge Transport and Energy Level in Solar Cells Based on Polymer/Fullerene Bulk Heterojunction

High Efficiencies in Nanoscale Poly(3-‎Hexylthiophene)/Fullerene Solar Cells

   A modified morphology was introduced for poly(3-hexylthiophene):phenyl-C71-butyric acid methyl ester (P3HT:PC71BM) bulk heterojunction (BHJ) solar cells by thermal and solvent annealing treatments in the presence of hydrophilic-hydrophobic block copolymers. Power conversion efficiency (PCE) plummet was prohibited during both thermal and solvent treatments for all BHJ devices modified wit...

Morphology of polymer/fullerene bulk heterojunction solar cells

Within the different organic photovoltaic devices the conjugated polymer/fullerene bulk heterojunction approach is one of the foci of today’s research interest. These devices are highly dependent on the solid state nanoscale morphology of the two components (donor/acceptor) in the photoactive layer. The need for finely phase separated polymer–fullerene blends is expressed by the limited exciton...

Room to Improve Conjugated Polymer-Based Solar Cells: Understanding How Thermal Annealing Affects the Fullerene Component of a Bulk Heterojunction Photovoltaic Device

We examine how thermal annealing affects the fullerene network in conjugated polymer bulk heterojunction (BHJ) solar cells. We begin by creating electron-only devices with a BHJ geometry by blending the fullerene derivative [6,6]-phenyl-C61-butyric-acid-methyl-ester (PCBM) with polystyrene (PS). These electron-only PS:PCBM diodes function even with a poly(ethylenedioxithiophene):poly(styrenesul...